hyperconjugation信息详情
超共轭效应
Natural bond orbital analysis shows that these H-bonds can be interpreted with the theory of inter-and intra-molecular hyperconjugation and rehybridization.───自然键轨道分析表明分子内与分子间超共轭和重杂化理论可以解释这些氢键的形成机制。
hyperconjugation between lone-pair of nitrogen atoms and nitrogen-nitrogen bonds, or among nitrogen-nitrogen bonds play a significant role on the nitrogen-nitrogen bond length.───氮原子孤对电子与氮氮键以及氮氮键相互之间的超共轭作用是影响氮氮键长的重要因素。
We summarized the hyperconjugation and its influence to physical property and its development.───综述了超共轭效应及其对物理性质的影响,以及超共轭理论的发展。
Natural bond orbital analysis shows that these H-bonds can be interpreted with the theory of inter-and intra-molecular hyperconjugation and rehybridization.
The hyperconjugation between lone-pair of nitrogen atoms and nitrogen-nitrogen bonds, or among nitrogen-nitrogen bonds play a significant role on the nitrogen-nitrogen bond length.
Thus, theexistance of "hyperconjugation", in electronic theory of organic chemistry is con-firmed intuitively.